Dr. Blackstock's Publication List

1. "Analysis for nitrosourea antitumor agents by gas chromatography-mass spectrometry." Smith, R. G.; Blackstock, S. C.; Cheung, L. K.; Loo, T. L. Anal. Chem. 53, 1205-8 (1981).

2. "One-electron oxidation of tetrasubstituted hydrazides and dihydrazides." Nelsen, S. F.; Blackstock, S. C.; Rumack, D. T. J. Am. Chem. Soc. 105, 3115-19 (1983).

3. "Diels-Alder reaction of protonated azo compounds. Isolation of a tetraalkyldiazenium dication." Nelsen, S. F.; Blackstock, S. C.; Frigo, T. B. J. Am. Chem. Soc. 106, 3366-7 (1984).

4. "On charge distribution in diazenium salts." Nelsen, S. F.; Blackstock, S. C. J. Org. Chem. 49, 1134-5 (1984).

5. "Measurement of hydrazine-hydrazine radical cation self-exchange electron-transfer rates by proton NMR." Nelsen, S. F.; Blackstock, S. C. J. Am. Chem. Soc. 107, 7189-90 (1985).

6. "Syn and anti bent hydrazine radical cations. Effect of s,p mixing on spectral properties." Nelsen, S. F.; Blackstock, S. C.; Yumibe, N. P.; Frigo, T. B.; Carpenter, J. E.; Weinhold, F. J. Am. Chem. Soc. 107, 143-9 (1985).

7. "Steric and conjugational electronic effects on the configuration of acylated hydrazines." Agmon, I.; Kaftory, M.; Nelsen, S. F.; Blackstock, S. C. J. Am. Chem. Soc. 108, 4477-84 (1986).

8. "Crystal structures of two syn bent tetraalkylhydrazines, their radical cations, and a dication." Nelsen, S. F.; Blackstock, S. C.; Haller, K. J. Tetrahedron 42, 6101-9 (1986).

9. "Proton-driven Diels-Alder reaction of azo compounds with cyclic dienes." Nelsen, S. F.; Blackstock, S. C.; Frigo, T. B. Tetrahedron 42, 1769-77 (1986).

10. "Azoalkanes as electron donors in charge-transfer complexes. Molecular structures with sacrificial (π*,σ*) and increvalent (ω) electron acceptors." Blackstock, S. C.; Kochi, J. K. J. Am. Chem. Soc. 109, 2484-96 (1987).

11. "Charge-transfer interactions of amines with tetrahalomethanes. X-ray crystal structures of the donor-acceptor complexes of quinuclidine and diazabicyclo [2.2.2]octane with carbon tetrabromide." Blackstock, S. C.; Lorand, J. P.; Kochi, J. K. J. Org. Chem. 52, 1451-60 (1987).

12. "Identity of 3,4-dimethylenethiophene reactive intermediates from diazene and bis-allene precursors. Correlation of singlet biradical reactivity in the tetramethyleneethane and trimethylenemethane series." Greenberg, M. M.; Blackstock, S. C.; Berson, J. A. Tetrahedron Lett. 28, 4263-6 (1987).

13. "One-electron oxidation equilibria for acylated hydrazines." Nelsen, S. F.; Blackstock, S. C.; Petillo, P. A.; Agmon, I.; Kaftory, M. J. Am. Chem. Soc. 109, 5724-31 (1987).

14. "Estimation of inner shell Marcus terms for amino nitrogen compounds by molecular orbital calculations." Nelsen, S. F.; Blackstock, S. C.; Kim, Y. J. Am. Chem. Soc. 109, 677-82 (1987).

15. "Comparison of free energy changes for nitrogen inversion and electron loss. 2. 8-Azabicyclo[3.2.1]octyl and 7-azabicyclo[2.2.1]heptyl systems." Nelsen, S. F.; Blackstock, S. C.; Steffek, D. J.; Cunkle, G. T.; Kurtzweil, M. L. J. Am. Chem. Soc. 110, 6149-53 (1988).

16. "Ground-state multiplicities of 3,4-dimethylenefuran and 3,4-dimethylenethiophene. Experimental tests of ab initio and semiempirical theories of heteroatom-bridged disjoint biradicals." Greenberg, M. M.; Blackstock, S. C.; Stone, K. J.; Berson, J. A. J. Am. Chem. Soc. 111, 3671-9 (1989).

17. "Solvent effects on self-electron-transfer rate constants for a sesquibicyclic hydrazine." Nelsen, S. F.; Kim, Y.; Blackstock, S. C. J. Am. Chem. Soc. 111, 2045-51 (1989).

18. "Heterocyclic aromatic non-Kekule molecules. Synthesis and solution-phase chemistry of the singlet biradicals 3,4-dimethylenefuran and 3,4-dimethylenethiophene." Stone, K. J.; Greenberg, M. M.; Blackstock, S. C.; Berson, J. A. J. Am. Chem. Soc. 111, 3659-71 (1989).

19. "Structure of the carrier of the cross-polarization magic angle spinning carbon-13 nuclear magnetic resonance signal assigned to 3,4-dimethylenethiophene. Multiple position-labeling and chemical trapping in annealed glasses." Greenberg, M. M.; Blackstock, S. C.; Berson, J. A.; Merrill, R. A.; Duchamp, J. C.; Zilm, K. W. J. Am. Chem. Soc. 113, 2318-19 (1991).

20. "1,1'-Azonorbornane radical cation. A solution-stable azoalkane radical cation." Mendicino, M. E.; Blackstock, S. C. J. Am. Chem. Soc. 113, 713-15 (1991).

21. "Triplet Dication and Quartet Trication of a Triaminobenzene." Stickley, K. R.; Blackstock, S. C. J. Am. Chem. Soc. 116, 11576-7 (1994).

22. "Pericyclic Arrays in the Solid State. Azooxide and Azodioxide Donor-Acceptor Complexes with Tetracyanoethylene." Blackstock, S. C.; Poehling, K.; Greer, M. L. J. Am. Chem. Soc. 117, 6617-18 (1995).

23. "Azodioxide Radical Cations." Greer, M. L.; Sarker, H.; Mendicino, M. E.; Blackstock, S. C. J. Am. Chem. Soc. 117, 10460-7 (1995).

24. "Trimethylenemethane Radical Cation Chemistry from a Diazene Precursor." Painter, S. L.; Blackstock, S. C. J. Am. Chem. Soc. 117, 1441-2 (1995).

25. "Cation radicals of 1,3,5-tris(diarylamino)benzenes." Stickley, K. R.; Blackstock, S. C. Tetrahedron Lett. 36, 1585-8 (1995).

26. "Complexes of Oxygenated trans-Azoalkanes and Tetracyanoethylene. The Interaction of π Oxygen Dipoles with an Electron Poor Alkene." Greer, M. L.; Blackstock, S. C. J. Org. Chem. 61, 7895-7903 (1996).

27. "Synthesis, Structure, and Conformational Dynamics of Bridgehead-Substituted Nitrosamines. Di-1-adamantylnitrosamine and Di-1-norbornylnitrosamine." Sarker, H.; Greer, M. L.; Blackstock, S. C. J. Org. Chem. 61, 3177-82 (1996).

28. "Supramolecular networks via pyridine N-oxide CH...O hydrogen bonding in the crystal structures of 2,2'-dithiobis(pyridine N-oxide) and its complexes with 1,2,4,5-tetracyanobenzene and pyromellitic dianhydride." Bodige, S. G.; Rogers, R. D.; Blackstock, S. C. Chem. Commun., 1669-1670 (1997).

29. "Nitrosamine/2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) Complexes and the Formation of Donor-Appended DDQ Chains in the Solid State." Greer, M. L.; Blackstock, S. C. J. Am. Chem. Soc. 119, 11343-11344 (1997).

30. "Solid-state complexes of quinoxaline- and phenazine-N,N'-dioxide donors with tetracyanoethylene. Crystal engineering via donor-acceptor interactions." Greer, M. L.; Duncan, J. R.; Duff, J. L.; Blackstock, S. C. Tetrahedron Lett. 38, 7665-7668 (1997).

31. "Pyrazinedioxide-tetracyanoethylene arrays in the solid state - new donor-acceptor interactions for crystal engineering." Greer, M. L.; McGee, B. J.; Rogers, R. D.; Blackstock, S. C. Angew. Chem., Int. Ed. 36, 1864-1866 (1997).

32. "Facile Ring Opening of Tertiary Aminocyclopropanes by Photooxidation." Lee, J.; U, J. S.; Blackstock, S. C.; Cha, J. K. J. Am. Chem. Soc. 119, 10241-10242 (1997).

33. "Isolable polyradical cations of polyphenylenediamines with populated high-spin states." Stickley, K. R.; Selby, T. D.; Blackstock, S. C. J. Org. Chem. 62, 448-449 (1997).

34. "Azoalkane-DDQ arrays in the solid state. New donor-acceptor interactions for crystal engineering." Greer, M. L.; Blackstock, S. C. Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 313, 55-64 (1998).

35. "Intramolecular [3 + 2] annulation of olefin-tethered cyclopropylamines." Ha, J. D.; Lee, J.; Blackstock, S. C.; Cha, J. K. J. Org. Chem. 63, 8510-8514 (1998).

36. "Preparation of a Redox-Gradient Dendrimer. Polyamines Designed for One-Way Electron Transfer and Charge Capture." Selby, T. D.; Blackstock, S. C. J. Am. Chem. Soc. 120, 12155-12156 (1998).

37. "Polyradical cations of high spin." Blackstock, S. C.; Selby, T. D. Magnet. Prop. Org. Mater., 165-178 (1999).

38. "Organic crystal engineering with heterocyclic N-oxides. Donor-acceptor bonding and CH...O hydrogen bonding in a pyrazine dioxide-pyromellitic dianhydride cocrystal." Bodige, S. G.; Selby, T. D.; McKay, S. E.; Blackstock, S. C. Trans. Amer. Crystallograph. Assoc. 33, 135-143 (1999).

39. "Heterocyclic N-oxide CH...O hydrogen bonding. Part 3. Crystal packing of 2,2'-bipyridine-1,1'-dioxide and pyridine N-oxide." Bodige, S. G.; Zottola, M. A.; McKay, S. E.; Blackstock, S. C. Cryst. Eng. 1, 243-253 (1999).

40. "Macrocyclic Poly Arylamines for Rigid Connection of Poly Radical Cation Spins." Selby, T. D.; Blackstock, S. C. Org. Lett. 1, 2053-2055 (1999).

41. "Naphthlenediamine Diradical Dications. Triplet Dications of 2,7-diaminonaphthalene and 2,7-Bis(phenylenediamino)naphthalene." Selby, T. D.; Blackstock, S. C. J. Am. Chem. Soc. 121, 7152-7153 (1999).

42. "Reactivity of the Gaseous Radical Cations of Trimethylenemethane and 2-Isopropylidenecyclopentane-1,3-diyl." Chou, P. K.; Gao, L.; Tichy, S. E.; Painter, S. L.; Blackstock, S. C.; Kenttaemaa, H. I. J. Phys. Chem. A 104, 5530-5534 (2000).

43. "A Chiral 2-D Donor-Acceptor Array of a Bipyrazine N-Oxide and Tetracyanoethylene." McGee, B. J.; Sherwood, L. J.; Greer, M. L.; Blackstock, S. C. Org. Lett. 2, 1181-1184 (2000).

44. "Triamino-s-triazine Triradical Trications. An Experimental Study of Triazine as a Magnetic Coupling Unit." Selby, T. D.; Stickley, K. R.; Blackstock, S. C. Org. Lett. 2, 171-174 (2000).

45. "Growth and characterization of poly(arylamine) thin films prepared by vapor deposition." Szulczewski, G. J.; Selby, T. D.; Kim, K. Y.; Hassenzahl, J. D.; Blackstock, S. C. J. Vac. Sci. Technol., A 18, 1875-1880 (2000).

46. "Radical Cation-Mediated Annulation. Stereoselective Construction of Bicyclo[5.3.0]decan-3-ones by Aerobic Oxidation of Cyclopropylamines." Lee, H. B.; Sung, M. J.; Blackstock, S. C.; Cha, J. K. J. Am. Chem. Soc. 123, 11322-11324 (2001).

47. "Oxidation methods for aromatic diazines: substituted pyrazine-N-oxides, pyrazine-N,N'-dioxides, and 2,2':6',2"-terpyridine-1,1"-dioxide." McKay, S. E.; Sooter, J. A.; Bodige, S. G.; Blackstock, S. C. Heterocyclic Commun. 7, 307-312 (2001).

48. "Patterned Redox Arrays of Polyarylamines II. Growth of Thin Films and Their Electrochemical Behavior." Kim, K.-Y.; Hassenzahl, J. D.; Selby, T. D.; Szulczewski, G. J.; Blackstock, S. C. Chem. Mater. 14, 1691-1694 (2002).

49. "Patterned redox arrays of polyarylamines I. Synthesis and electrochemistry of a p-phenylenediamine and arylamino-appended p-phenylenediamine arrays." Selby, T. D.; Kim, K.-Y.; Blackstock, S. C. Chem. Mater. 14, 1685-1690 (2002).

50. "Patterned Redox Arrays of Polyarylamines III. Effect of Molecular Structure and Oxidation Potential on Film Morphology and Hole-Injection in Single-Layer Organic Diodes." Li, J. C.; Kim, K. Y.; Blackstock, S. C.; Szulczewski, G. J. Chem. Mater. 16, 4711-4714 (2004).

51. "Pyrazine-N,N'-dioxide/tetracyanoethylene electron donor-acceptor bonding and the effect of donor steric demand and symmetry on the cocrystal assembly." Kucharski, T. J.; Oxsher, J. R.; Blackstock, S. C. Tetrahedron Lett. 47, 4569-4572 (2006).

52. "Interfaces between Metal and Arylamine Molecular Films As Probed with the Anode Interfacial Engineering Approach in Single-Layer Organic Diodes." Li, J. C.; Blackstock, S. C.; Szulczewski, G. J. J. Phys. Chem. B 110, 17493-17497 (2006).

53. "A molecular salt of tricyanomethanide anion and a N,N'-dianisylphenazinium dication: cooperative affects of methoxy...methoxy and C≡N...N⁺ intermolecular contacts." McKay, S. E.; Wheeler, K. A.; Blackstock, S. C. CrystEngComm 8, 129-131 (2006).

54. "Single molecule charging by atomic force microscopy." Chotsuwan, C.; Blackstock, S. C. J. Am. Chem. Soc. 130, 12556-12557 (2008).

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