Dr. Shaughnessy's Publication List

1. "A facile method for the preparation of functionalized 2-halo-1-olefins." Zhu, L.-S.; Shaughnessy, K. H.; Rieke, R. D. Synth. Comm. 23, 525-529 (1993).

2. "Carbometalation of α,ω-Dienes and Olefins Catalyzed by Zirconocenes." Shaughnessy, K. H.; Waymouth, R. M. J. Am. Chem. Soc. 117, 5873-5874 (1995).

3. "Highly regioselective cyclocarboxylation of nonconjugated dienes catalyzed by palladium." Shaughnessy, K. H.; Waymouth, R. M. Organometallics 16, 1001-1007 (1997).

4. "Palladium-catalyzed inter- and intramolecular α-arylation of amides. Application of intramolecular amide arylation to the synthesis of oxindoles." Shaughnessy, K. H.; Hamann, B. C.; Hartwig, J. F. J. Org. Chem. 63, 6546-6553 (1998).

5. "Enantio- and diastereoselective catalytic carboalumination of 1-alkenes and α,ω-dienes with cationic zirconocenes: scope and mechanism." Shaughnessy, K. H.; Waymouth, R. M. Organometallics 17, 5728-5745 (1998).

6. "Room temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand." Hartwig, J. F.; Kawatsura, M.; Hauck, S. I.; Shaughnessy, K. H.; Alcazar-Roman, L. M. J. Org. Chem. 64, 5575-5580 (1999).

7. "A fluorescence-based assay for high throughput screening of coupling reactions. Application to Heck coupling processes." Shaughnessy, K. H.; Kim, P.; Hartwig, J. F. J. Am. Chem. Soc. 121, 2123-2132 (1999).

8. "Transition metal-catalyzed process for preparing arylamines," Hartwig, J. F.; Kawatsura, M.; Hauck, S. I.; Shaughnessy, K. H.; Alcazar-Roman, L. M., U.S. 6100398, 2000. Chem. Abs. 133:150343.

9. "Sterically demanding, water-soluble alkylphosphines as ligands for high activity Suzuki coupling of aryl bromides in aqueous solvents." Shaughnessy, K. H.; Booth, R. S. Org. Lett. 3, 2757-2759 (2001).

10. "Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions." Stambuli, J. P.; Stauffer, S. R.; Shaughnessy, K. H.; Hartwig, J. F. J. Am. Chem. Soc. 123, 2677-2678 (2001).

11. "Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts." Klingshirn, M. A.; Broker, G. A.; Holbrey, J. D.; Shaughnessy, K. H.; Rogers, R. D. Chem. Commun., 1394-1395 (2002).

12. "Acid-mediated, chromium-catalyzed allylation of aldehydes." Shaughnessy, K. H.; Huang, R. Synth. Comm. 32, 1923-1928 (2002).

13. "Synthesis, properties, and NMR studies of a C8-phenylguanine modified oligonucleotide that preferentially adopts the Z DNA conformation." Gannett, P. M.; Heavner, S.; Daft, J. R.; Shaughnessy, K. H.; Epperson, J. D.; Greenbaum, N. L. Chem. Res. Toxicol. 16, 1385-1394 (2003).

14. "Polar, non-coordinating ionic liquids as solvents for coordination polymerization of olefins," Shaughnessy, K. H.; Klingshirn, M. A.; P'Pool, S. J.; Holbrey, J. D.; Rogers, R. D. In Ionic Liquids as Green Solvents: Progress and Prospects; Rogers, R. D. and Seddon, K. R., Ed.; American Chemical Society: Washington, DC, 2003, pp 300-313.

15. "Efficient, one-step Suzuki arylation of unprotected halonucleosides using water-soluble palladium catalysts." Western, E. C.; Daft, J. R.; Johnson, E. M., II; Gannett, P. M.; Shaughnessy, K. H. J. Org. Chem. 68, 6767-6774 (2003).

16. "Aqueous-phase, palladium-catalyzed cross-coupling of aryl bromides under mild conditions, using water-soluble, sterically demanding alkylphosphines." DeVasher, R. B.; Moore, L. R.; Shaughnessy, K. H. J. Org. Chem. 69, 7919-7927 (2004).

17. "Efficient aqueous-phase Heck and Suzuki couplings of aryl bromides using tri(4,6-dimethyl-3-sulfonatophenyl)phosphine trisodium salt (TXPTS)." Moore, L. R.; Shaughnessy, K. H. Org. Lett. 6, 225-228 (2004).

18. "Experimental and computational study of steric and electronic effects on the coordination of bulky, water-soluble alkylphosphines to palladium under reducing conditions: correlation to catalytic activity." DeVasher, R. B.; Spruell, J. M.; Dixon, D. A.; Broker, G. A.; Griffin, S. T.; Rogers, R. D.; Shaughnessy, K. H. Organometallics 24, 962-971 (2005).

19. "t-Bu-Amphos-RhCl₃·3H₂O: a highly recyclable catalyst system for the cross-coupling of aldehydes and aryl- and alkenylboronic acids in aqueous solvents." Huang, R.; Shaughnessy, K. H. Chem. Commun., 4484-4486 (2005).

20. "Palladium-catalyzed hydroesterification of styrene derivatives in the presence of ionic liquids." Klingshirn, M. A.; Rogers, R. D.; Shaughnessy, K. H. J. Organomet. Chem. 690, 3620-3626 (2005).

21. "Kinetic study of oxidative addition of methyl iodide to Vaska's complex in ionic liquids." P'Pool, S. J.; Klingshirn, M. A.; Rogers, R. D.; Shaughnessy, K. H. J. Organomet. Chem. 690, 3522-3528 (2005).

22. "Palladium-catalyzed cross-coupling in aqueous media: recent progress and current applications." Shaughnessy, K. H.; DeVasher, R. B. Curr. Org. Chem. 9, 585-604 (2005).

23. "Di-t-butyl(ferrocenylmethyl)phosphine: air-stability, structural characterization, coordination chemistry, and application to palladium-catalyzed cross-coupling." Sliger, M. D.; Broker, G. A.; Griffin, S. T.; Rogers, R. D.; Shaughnessy, K. H. J. Organomet. Chem. 690, 1478-1486 (2005).

24. "Promoting effect of ionic liquids on ligand substitution reactions." Sliger, M. D.; P'Pool, S. J.; Traylor, R. K.; McNeil, J., III; Young, S. H.; Hoffman, N. W.; Klingshirn, M. A.; Rogers, R. D.; Shaughnessy, K. H. J. Organomet. Chem. 690, 3540-3545 (2005).

25. "Inhibitory effects of the guanine moiety on the Suzuki couplings of unprotected halonucleosides in aqueous media." Western, E. C.; Shaughnessy, K. H. J. Org. Chem. 70, 6378-6388 (2005).

26. "Bulky alkylphosphines with neopentyl substituents as ligands in the amination of aryl bromides and chlorides." Hill, L. L.; Moore, L. R.; Huang, R.; Craciun, R.; Vincent, A. P.; Dixon, D. A.; Chou, J.; Woltermann, C. J.; Shaughnessy, K. H. J. Org. Chem. 71, 5117-5125 (2006).

27. "Beyond TPPTS: new approaches to the development of efficient palladium-catalyzed aqueous-phase cross-coupling reactions." Shaughnessy, K. H. Eur. J. Org. Chem., 1827-1835 (2006).

28. "Water-Soluble Palladacycles as Precursors to Highly Recyclable Catalysts for the Suzuki Coupling of Aryl Bromides in Aqueous Solvents," Huang, R. and Shaughnessy, K. H. Organometallics 25, 4105-4112 (2006).

29. "Synthesis and Characterization of Water-Soluble Silver and Palladium Imidazol-2-ylidene Complexes with Non-Coordinated Anionic Substituents, " Moore, L. R.; Cooks, S. M; Anderson, M. S.; Schanz, H.-J.; Griffin, S. T.; Rogers, R. D.; Kirk, M. C; Shaughnessy, K. H. Organometallics 25, 5151-5158 (2006).

30. "A Selective and Tin-Free Pd-Catalyzed Phenylselenylation of Aryl Bromides" Cho, J. H.; Brown, F. V.; Shaughnessy, K. H. Main Group Chem. 6, 201-214 (2007).

31. "Sterically Demanding, Sulfonated, Triarylphosphines:  Application to Palladium-Catalyzed Cross-Coupling, Steric and Electronic Properties, and Coordination Chemistry," Moore, L. R.; Western, E. C.; Craciun, R.; Spruell, J. M.; Dixon, D. A.; O'Halloran, K. P.; Shaughnessy, K. H. Organometallics, 27, 576-593 (2008).

32. "Neopentylphosphines as Effective Ligands in Palladium-Catalyzed Cross-Couplings of Aryl Bromides and Chlorides," Hill, L. L.; Smith, J. M.; Brown, W. S.; Moore, L. R.; Guevara, P.: Pair, E. S.; Porter, J.; Chou, J.; Wolterman, C. J.; Craciun, R.; Dixon, D. A.; Shaughnessy, K. H. Tetrahedron, 64, 6920-6934 (2008).

33. "Sterically-Demanding, Zwitterionic Trialkylphosphonium Sulfonates as Air-Stable Ligand Precursors for Efficient Palladium-Catalyzed Cross-Couplings of Aryl Bromides and Chlorides," Brown, W. S.; Boykin, D. D.; Sonnier, M. Q., Jr.; Clark, W. D.; Brown, F. V.; Shaughnessy, K. H. Synthesis,1965-1970 (2008).

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