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Dr. Thrasher's Publication List

1. "Reactions of pentafluorosulfanyliminodihalosulfanes, SF5N:SX2, with nucleophiles. Preparation and characterization of pentafluorosulfanylsulfinylamine, SF5N:S:O." Thrasher, J. S.; Iannaccone, G. A.; Hosmane, N. S.; Maurer, D. E.; Clifford, A. F. J. Fluorine Chem. 18, 537-51 (1981).

2. "Reactions of [(pentafluorosulfanyl)imino]difluorosulfane, SF5N:SF2, with titanium(IV) chloride, TiCl4, tin(IV) chloride, SnCl4, and antimony(V) chloride, SbCl5. Preparation and characterization of [(pentafluorosulfanyl)imino]chlorofluorosulfane, SF5N:SClF." Thrasher, J. S.; Hosmane, N. S.; Maurer, D. E.; Clifford, A. F. Inorg. Chem. 21, 2506-8 (1982).

3. "Preparation and characterization of N-(pentafluorosulfanyl)imine derivatives." Thrasher, J. S.; Clifford, A. F. J. Fluorine Chem. 19, 411-25 (1982).

4. "Acylations of pentafluorosulfanylamine, SF5NH2." Thrasher, J. S.; Howell, J. L.; Clifford, A. F. Inorg. Chem. 21, 1616-22 (1982).

5. "Reactions of N-pentafluorosulfanylurethanes and thiolurethanes with phosphorus pentachloride." Thrasher, J. S.; Clifford, A. F. J. Fluorine Chem. 23, 593-6 (1983).

6. "Reactions of pentafluorosulfanyldichloroamine." Thrasher, J. S.; Seppelt, K. Z. Anorg. Allg. Chem. 507, 7-11 (1983).

7. "A new route to tellurium-nitrogen compounds." Thrasher, J. S.; Seppelt, K. Angew. Chem. 95, 813 (1983).

8. "Pentafluoroselenium isocyanate and pentafluorotellurium isocyanate, F5SeN:C:O and F5TeN:C:O." Huppmann, P.; Kloeter, G.; Thrasher, J. S.; Seppelt, K.; DesMarteau, D. D. Inorg. Chem. 23, 2217-19 (1984).

9. "N-Bromodifluoromethanimine." O'Brien, B. A.; Thrasher, J. S.; Bauknight, C. W., Jr.; Robin, M. L.; DesMarteau, D. D. J. Am. Chem. Soc. 106, 4266-7 (1984).

10. "Acylations of pentafluorosulfanylamine, SF5NH2. Part II. Reactions of N-(pentafluorosulfanyl)carbamoyl fluoride, SF5NHCOF, and N-(pentafluorosulfanyl)perfluorosuccinimide, cyclo-SF5NCOCF2CF2C(O)." Thrasher, J. S.; Howell, J. L.; Clifford, A. F. J. Fluorine Chem. 24, 431-42 (1984).

11. "Reactions of pentafluorosulfanyl isocyanate and isothiocyanate." Thrasher, J. S.; Howell, J. L.; Clifford, A. F. Chem. Ber. 117, 1707-25 (1984).

12. "Solvent effects in fluorine-19 NMR spectroscopy: nonuniform shifting of the axial and equatorial fluorine resonances of the pentafluorosulfanyl group." Thrasher, J. S.; Howell, J. L.; Maurer, D. E.; Clifford, A. F. J. Fluorine Chem. 24, 205-9 (1984).

13. "Nitrosyl pentafluorotellurate(VI)." Thrasher, J. S.; Seppelt, K. Z. Anorg. Allg. Chem. 529, 85-8 (1985).

14. "Tellurium-nitrogen compounds. Reactions of ((dichloromethylene)amino)pentafluorotellurium, TeF5N:CCl2, and its derivatives." Thrasher, J. S.; Seppelt, K. Inorg. Chem. 24, 4171-7 (1985).

15. "(Perfluoroalkylimino)selenyl chlorides." Thrasher, J. S.; Bauknight, C. W., Jr.; DesMarteau, D. D. Inorg. Chem. 24, 1598-9 (1985).

16. "(Fluorocarbonyl)imidosulfurous difluoride." Thrasher, J. S. Inorg. Synth. 24, 10-12 (1986).

17. "Tetraisocyanatosilane." Thrasher, J. S. Inorg. Synth. 24, 99-101 (1986).

18. "An unusual methoxy group migration: synthesis of cis-CH3OSF4NCO and cis-CH3OSF4NHC(O)OCH3." Thrasher, J. S.; Howell, J. L.; Clark, M.; Clifford, A. F. J. Am. Chem. Soc. 108, 3526-7 (1986).

19. "Tetrakis(pentafluorosulfanyl)hydrazine and bis(pentafluorosulfanyl)aminyl radical." Thrasher, J. S.; Nielsen, J. B. J. Am. Chem. Soc. 108, 1108-9 (1986).

20. "Crystal and molecular structure of S-methyl (pentafluorosulfanyl)thiocarbamate." Bott, S. G.; Clark, M.; Thrasher, J. S.; Atwood, J. L. J. Cryst. Spectr. Res. 17, 187-96 (1987).

21. "An ab initio study of the possible isomers and conformations of N-(trifluoromethyl)fluoromethanimine, CF3N:CHF." Clark, M.; Thrasher, J. S. Theochem 38, 67-74 (1987).

22. "Superconductivity in rapidly cooled gadolinium barium copper oxide (Gd3Ba3Cu4Oz)." Robinson, D. A.; Morrobel-Sosa, A.; Alexander, C., Jr.; Thrasher, J. S.; Asavaroengchai, C.; Metzger, R. M. NATO ASI Series, Series B: Physics 168, 373-6 (1987).

23. "A relaxation time study of sulfur pentafluoride reorientation in solid tetrakis(pentafluorosulfanyl)hydrazine, (SF5)2NN(SF5)2." Choudhury, M. R.; Harrell, J. W., Jr.; Nielsen, J. B.; Thrasher, J. S. J. Chem. Phys. 88, 2135-8 (1988).

24. "Zero resistance at 100 K in the superconductor gadolinium barium copper oxide (GdBa2Cu3O7-z)." Robinson, D. A.; Asavaroengchai, C.; Morrobel-Sosa, A.; Alexander, C., Jr.; Metzger, R. M.; Thrasher, J. S.; Maginnis, M. A.; Stanley, D. A. Journal of Physics C: Solid State Physics 21, 4091-6 (1988).

25. "Reactions of tellurium chloride pentafluoride, TeF5Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = methyl or ethyl." Thrasher, J. S.; Clark, M.; Morken, P. A. J. Fluorine Chem. 39, 235-43 (1988).

26. "Bis[(pentafluorothio)(trifluoromethyl)amido]mercury, Hg[N(CF3)SF5]2, and bis[(pentafluorotelluro)(trifluoromethyl)amido]mercury, Hg[N(CF3)TeF5]2." Thrasher, J. S.; Nielsen, J. B.; Bott, S. G.; McClure, D. J.; Morris, S. A.; Atwood, J. L. Inorg. Chem. 27, 570-5 (1988).

27. "Carbon monoxide oxygenase activity of cytochrome cd1." Timkovich, R.; Thrasher, J. S. Biochemistry 27, 5383-8 (1988).

28. "Microwave spectrum and molecular structure of pentafluorosulfanyliminosulfur difluoride and a comparison with a theoretical equilibrium structure." White, R. M.; Bailey, S. R.; Graybeal, J. D.; Thrasher, J. S.; Palmer, M. H. J. Mol. Spectrosc. 129, 243-53 (1988).

29. "Alkylidenesulfur difluorides: F5S(F3C)C:SF2 and (F3C)2C:SF2. Synthesis, structure and structure predictions." Damerius, R.; Seppelt, K.; Thrasher, J. S. Angew. Chem. 101, 783-5 (1989).

30. "Sulfur pentafluoride isocyanide (SF5NC)." Thrasher, J. S.; Madappat, K. V. Angew. Chem. 101, 1284-6 (1989).

31. "LAOCOON PC: NMR simulation on a personal computer." Clark, M.; Thrasher, J. S. J. Chem. Ed. 67, 235-6 (1990).

32. "Industrial chemistry: an intensive short course made possible through the cooperation of area chemical industry." Gumprecht, D. L.; Thrasher, J. S. J. Chem. Ed. 67, 321-2 (1990).

33. "Synthesis of new perfluorotertiary amines containing geminal pentafluorosulfanyl. SF5 groups." Nielsen, J. B.; Thrasher, J. S. J. Fluorine Chem. 48, 407-20 (1990).

34. "Polynitroaliphatic explosives containing pentafluorosulfanyl (SF5) group: the selection and study of a model compound." Sitzmann, M. E.; Gilligan, W. H.; Ornellas, D. L.; Thrasher, J. S. J. Energ. Mater. 8, 352-74 (1990).

35. "An improved synthesis of dichlorofluoramine FNCl2." Thrasher, J. S.; Desmarteau, D. D. J. Fluorine Chem. 52, 51-5 (1991).

36. "The conjunction of aromaticity and hypervalency: the C5H5SF3 molecule 1,1,1-trifluorothiabenzene." Xie, Y.; Schaefer, H. F., III; Thrasher, J. S. Theochem 80, 247-67 (1991).

37. ""Naked" pentafluorosulfate (1-) anion: the crystal and molecular structure of [Cs+·(18-crown-6)2][SF5-]." Clark, M.; Kellen-Yuen, C. J.; Robinson, K. D.; Zhang, H.; Yang, Z. Y.; Madappat, K. V.; Fuller, J. W.; Atwood, J. L.; Thrasher, J. S. Eur. J. Solid State Inorg. Chem. 29, 809-33 (1992).

38. "Addition of sulfur trioxide to pentafluorothio (SF5) (pentafluoro-l6-sulfanyl) containing fluoroolefins." Mohtasham, J.; Terjeson, R. J.; Gard, G. L.; Scott, R. A.; Madappat, K. V.; Thrasher, J. S. Inorg. Synth. 29, 33-8 (1992).

39. "Pentafluoro(isocyanato)-l6-sulfane (SF5N=C=O)." Thrasher, J. S.; Clark, M.; Nielsen, J. B.; Alvarado, C.; Anderson, M. T.; Steinke, G.; Meier, T.; Mews, R. Inorg. Synth. 29, 38-40 (1992).

40. "A computational study of the possible isomers and conformations of N-trifluoromethylformamide, CF3NHC(O)H, and N-hydroxymethylidenetrifluoromethylamine, CF3N=C(H)OH." Madappat, K. V.; Clark, M.; Thrasher, J. S. Theochem 104, 1-15 (1993).

41. "Alkali metal polyhydrogen fluorides. Useful halogen-exchange media." Fernandez, R. E.; Thrasher, J. S. ACS Symposium Series 555, 237-50 (1994).

42. "Inorganic fluorine chemistry. Toward the 21st century." Thrasher, J. S.; Strauss, S. H. ACS Symposium Series 555, 1-23 (1994).

43. "Experimental and theoretical research towards RfNCl3+ cations, where Rf = CF3, SF5, FC(O) and F." Sun, J.; Thrasher, J. S. J. Fluorine Chem. 71, 213-214 (1995).

44. "Pentacarbonyl chromium complexes of SF5-substituted isocyanides." Preugschat, D.; Thrasher, J. S. Z. Anorg. Allg. Chem. 622, 1411-1414 (1996).

45. "Reactions of poly-hexafluoropropylene oxide acids and their corresponding salts." Howell, J. L.; Hofmann, M. A.; Waterfeld, A.; Sipyagin, A. M.; Friesen, C. M.; Thrasher, J. S. J. Fluorine Chem. 89, 131-135 (1998).

46. "The effect of fluorine on the diastereoselectivity of the addition of a-oxy radicals to 3-fluoro-2,3-dihydro-1H-l6-thiophene-1,1-dione." Nowak, I.; Rogers, L. M.; Rogers, R. D.; Thrasher, J. S. J. Fluorine Chem. 99, 73-81 (1999).

47. "Toward the synthesis of novel fluorinated building blocks: 3,4-difluorothiophene-1,1-dioxide." Nowak, I.; Rogers, L. M.; Rogers, R. D.; Thrasher, J. S. J. Fluorine Chem. 93, 27-32 (1999).

48. "Crystal and molecular structures of trifluoroacrylonitrile, F2C:CF-CN, and trifluorovinyl isocyanide, F2C:CF-NC, by low-temperature x-ray crystallography and ab initio calculations." Buschmann, J.; Kleinhenz, S.; Lentz, D.; Luger, P.; Madappat, K. V.; Preugschat, D.; Thrasher, J. S. Inorg. Chem. 39, 2807-2812 (2000).

49. "Pentafluorosulfanylnitramide Salts." Sitzmann, M. E.; Gilardi, R.; Butcher, R. J.; Koppes, W. M.; Stern, A. G.; Thrasher, J. S.; Trivedi, N. J.; Yang, Z.-Y. Inorg. Chem. 39, 843-850 (2000).

50. "Preparation of the first ortho-substituted pentafluorosulfanylbenzenes." Sipyagin, A. M.; Bateman, C. P.; Tan, Y.-T.; Thrasher, J. S. J. Fluorine Chem. 112, 287-295 (2001).

51. "The direct synthesis of trifluoronitromethane, CF3NO2." Lu, N.; Thrasher, J. S. J. Fluorine Chem. 117, 181-184 (2002).

52. "1-Chloro-2,6-dinitro-4-[(perfluoroalkyl)thio]benzenes in the synthesis of heterocycles." Sipyagin, S. M.; Enshov, V. S.; Kashtanov, S. A.; Thrasher, J. S. Chem. Het. Compounds 38, 1375-1381 (2002).

53. "Crystal and molecular structures of the pentafluorosulfanyl compounds, SF5X (X = -NC, -CN, -NCO, -NCS and -NCCl2) by X-ray diffraction at low temperature." Buschmann, J.; Lentz, D.; Luger, P.; Perpetuo, G.; Preugschat, D.; Thrasher, J. S.; Willner, H.; Woelk, H.-J. Z. Anorg. Allg. Chem. 630, 1136-1142 (2004).

54. "The preparation of primary polyhexafluoropropylene oxide halides (poly-HFPO-CF2X where X = I, Br, Cl and F)." Howell, J. L.; Lu, N.; Perez, E. W.; Friesen, C. M.; Novak, I.; Waterfeld, A.; Thrasher, J. S. J. Fluorine Chem. 125, 1513-1518 (2004).

55. "New 4-pentafluorosulfanyl and 4-perfluoroalkylthio derivatives of 1-chloro-2-nitro- and 1-chloro-2,6-dinitrobenzenes." Sipyagin, A. M.; Enshov, V. S.; Kashtanov, S. A.; Bateman, C. P.; Mullen, B. D.; Tan, Y.-T.; Thrasher, J. S. J. Fluorine Chem. 125, 1305-1316 (2004).

56. "Synthesis of aryl perfluoroalkyl sulfides from aromatic disulfides." Sipyagin, A. M.; Enshov, V. S.; Kashtanov, S. A.; Potemkin, V. A.; Thrasher, J. S.; Waterfeld, A. Russ. Chem. Bull. 53, 420-434 (2004).

57. "Studies of the thermal behavior of Nafion membranes treated with aluminum(III)." Sun, L.; Thrasher, J. S. Polym. Degrad. Stability 89, 43-49 (2005).

58. "Low-temperature fluorination of fluoro-containing polymers." Allayarov, S. R.; Konovalova, T. A.; Waterfield, A.; Focsan, A. L.; Jackson, V.; Craciun, R.; Kispert, L. D.; Thrasher, J. S.; Dixon, D. A. J. Fluorine Chem. 127, 1294-1301 (2006).

59. "A convenient and efficient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic compounds." Dolbier, W. R.; Ait-Mohand, S.; Schertz, T. D.; Sergeeva, T. A.; Cradlebaugh, J. A.; Mitani, A.; Gard, G. L.; Winter, R. W.; Thrasher, J. S. J. Fluorine Chem. 127, 1302-1310 (2006).

60. "Synthesis of the long sought after compound pentafluoronitrosulfane, SF5NO2." Lu, N.; Kumar, H. P. S.; Fye, J. L.; Blanks, J. S.; Thrasher, J. S.; Willner, H.; Oberhammer, H. Angew. Chem., Int. Ed. 45, 938-940 (2006).

61. "Pentafluoronitrosulfane, SF5NO2." Lu, N.; Thrasher, J. S.; von Ahsen, S.; Willner, H.; Hnyk, D.; Oberhammer, H. Inorg. Chem. 45, 1783-1788 (2006).

62. "Combustible ionic liquids by design: is laboratory safety another ionic liquid myth?" Smiglak, M.; Reichert, W. M.; Holbrey, J. D.; Wilkes, J. S.; Sun, L.; Thrasher, J. S.; Kirichenko, K.; Singh, S.; Katritzky, A. R.; Rogers, R. D. Chem. Commun., 2554-2556 (2006).

63. "A modified accelerating rate calorimeter (ARC) with capabilities for handling gaseous samples under vacuum or an inert atmosphere." Sun, L.; Waterfeld, A.; Thrasher, J. S. J. Fluorine Chem. 127, 1436-1439 (2006).

64. "Improved thermal stability of perfluoropolyalkylethers (PFPAEs)." Howell, J. L.; Friesen, C. M.; Shtarov, A. B.; Thrasher, J. S.; Waterfeld, A.; Perez, E. W.; Sullivan, J. F. J. Synth. Lubr. 24, 227-234 (2007).

 

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