Department Faculty Publications

Chemistry Department faculty publications from 2001:

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1. "Dendralene-Type TTF Vinylogs Containing a 1,3-Diselenole Ring." Amaresh, R. R.; Liu, D.; Konovalova, T.; Lakshmikantham, M. V.; Cava, M. P.; Kispert, L. D. J. Org. Chem. 66, 7757-7764 (2001).

2. "Synthesis of 3,4-ethylenedioxyselenophene (EDOS): a novel building block for electron-rich π-conjugated polymers." Aqad, E.; Lakshmikantham, M. V.; Cava, M. P. Org. Lett. 3, 4283-4285 (2001).

3. "Studies of Cetylpyridinium Chloride and Cetylpyridinium Salicylate in Solution and Adsorbed on Silica Surfaces Using X- and W-Band Electron Paramagnetic Resonance Spectroscopy." Bakker, M. G.; Granger, E. L.; Smirnov, A. I. Langmuir 17, 2346-2356 (2001).

4. "Mutations in both sides of the photosystem I reaction center identify the phylloquinone observed by electron paramagnetic resonance spectroscopy." Boudreaux, B.; MacMillan, F.; Teutloff, C.; Agalarov, R.; Gu, F.; Grimaldi, S.; Bittl, R.; Brettel, K.; Redding, K. J. Biol. Chem. 276, 37299-37306 (2001).

5. "Effects of substrates on the self-assembling of FePt nanocrystals." Chen, M.; Nikles, D. E. Mater. Res. Soc. Symp. Proc. 674, U4.8.1-U4.8.6 (2001).

6. "Surface characterization of iron particles treated with a polyvinylchloride wetting binder." Chen, M.; Nikles, D. E. IEEE Trans. Magn. 37, 1637-1639 (2001).

7. "Synthesis and self-assembly of films containing FeCoPt nanoparticles." Chen, M.; Nikles, D. E. Mater. Res. Soc. Symp. Proc. 674, U4.7.1-U4.7.5 (2001).

8. "[4 + 3] Cycloaddition of Cyclopropanone Hemiacetals." Cho, S. Y.; Lee, H. I.; Cha, J. K. Org. Lett. 3, 2891-2893 (2001).

9. "The trail of chromium(III) in vivo from the blood to the urine: the roles of transferrin and chromodulin." Clodfelder, B. J.; Emamaullee, J.; Hepburn, D. D. D.; Chakov, N. E.; Nettles, H. S.; Vincent, J. B. J. Biol. Inorg. Chem. 6, 608-617 (2001).

10. "Dissociation of multiply charged negative ions for hirudin (54-65), fibrinopeptide B, and insulin A (oxidized)." Ewing, N. P.; Cassady, C. J. J. Am. Soc. Mass Spectrom. 12, 105-116 (2001).

11. "Gas-phase basicities for ions from bradykinin and its des-arginine analogues." Ewing, N. P.; Pallante, G. A.; Zhang, X.; Cassady, C. J. J. Mass Spectrom. 36, 875-881 (2001).

12. "On the UV curability and mechanical properties of novel binder systems derived from poly(ethylene terephthalate) (PET) waste for solventless magnetic tape manufacturing, 1 Acrylated oligoesters." Farahat, M. S.; Nikles, D. E. Macromol. Mater. Eng. 286, 695-704 (2001).

13. "Enhancement of post-receptor insulin signaling by trivalent chromium in hepatoma cells is associated with differential inhibition of specific protein-tyrosine phosphatases." Goldstein, B. J.; Zhu, L.; Hager, R.; Zilbering, A.; Sun, Y.; Vincent, J. B. J. Trace Elem. Exp. Med. 14, 393-404 (2001).

14. "Evidence for two active branches for electron transfer in photosystem I." Guergova-Kuras, M.; Boudreaux, B.; Joliot, A.; Joliot, P.; Redding, K. Proc. Nat. Acad. Sci. USA 98, 4437-4442 (2001).

15. "Amine-quinone polyimides as coatings that protect iron against corrosion." Han, M.; Bie, H.; Warren, G. W.; Nikles, D. E. Mater. Res. Soc. Symp. Proc. 629, FF5.17.1-FF5.17.6 (2001).

16. "Amine-quinone polyimides." Han, M.; Nikles, D. E. J. Polym. Sci., A 39, 4044-4049 (2001).

17. "Single Two-Electron Transfers vs Successive One-Electron Transfers in Polyconjugated Systems Illustrated by the Electrochemical Oxidation and Reduction of Carotenoids." Hapiot, P.; Kispert, L. D.; Konovalov, V. V.; Saveant, J.-M. J. Am. Chem. Soc. 123, 6669-6677 (2001).

18. "Thermal effects in self-assembled FePt nanoparticles with partial chemical ordering." Harrell, J. W.; Wang, S.; Nikles, D. E.; Chen, M. Appl. Phys. Lett. 79, 4393-4395 (2001).

19. "Carotenoids in Sol-Gels: Incorporation, Stability, and Sensitivity to Oxidant and Acid." He, Z.; Kispert, L. D. Chem. Mater. 13, 227-231 (2001).

20. "Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation." Huddleston, J. G.; Visser, A. E.; Reichert, W. M.; Willauer, H. D.; Broker, G. A.; Rogers, R. D. Green Chem. 3, 156-164 (2001).

21. "Effect of silane coupling agents on rheological properties of solventless magnetic ink." Huh, J. Y.; Woo, T.; Nikles, D. E. Polym. Mat. Sci. Eng. 85, 387-388 (2001).

22. "Fluorescence quenching by electron transfer in dendritic porphyrin chromophores." Kim, M. J.; Tang, H.; Nikles, D. E. Polym. Mat. Sci. Eng. 84, 854-855 (2001).

23. "On the stereochemistry of anion-accelerated [1,3]-sigmatropic rearrangement of 2-vinylcyclobutanols." Kim, S.-H.; Cho, S. Y.; Cha, J. K. Tetrahedron Lett. 42, 8769-8772 (2001).

24. "Detection of Anisotropic Hyperfine Components of Chemically Prepared Carotenoid Radical Cations: 1D and 2D ESEEM and Pulsed ENDOR Study." Konovalova, T. A.; Dikanov, S. A.; Bowman, M. K.; Kispert, L. D. J. Phys. Chem. B 105, 8361-8368 (2001).

25. "Photooxidation of Carotenoids in Mesoporous MCM-41, Ni-MCM-41 and Al-MCM-41 Molecular Sieves." Konovalova, T. A.; Gao, Y.; Schad, R.; Kispert, L. D.; Saylor, C. A.; Brunel, L.-C. J. Phys. Chem. B 105, 7459-7464 (2001).

26. "Theory of electrical rectification in a molecular monolayer." Krzeminski, C.; Delerue, C.; Allan, G.; Vuillaume, D.; Metzger, R. M. Phys. Rev. B: Condens. Matter 64, 085405/1-085405/6 (2001).

27. "Radical Cation-Mediated Annulation. Stereoselective Construction of Bicyclo[5.3.0]decan-3-ones by Aerobic Oxidation of Cyclopropylamines." Lee, H. B.; Sung, M. J.; Blackstock, S. C.; Cha, J. K. J. Am. Chem. Soc. 123, 11322-11324 (2001).

28. "Total Synthesis of Tropoloisoquinolines: Imerubrine, Isoimerubrine, and Grandirubrine." Lee, J. C.; Cha, J. K. J. Am. Chem. Soc. 123, 3243-3246 (2001).

29. "Formal Synthesis of (+)-Phorbol." Lee, K.; Cha, J. K. J. Am. Chem. Soc. 123, 5590-5591 (2001).

30. "Temperature effects on polymer-based aqueous biphasic extraction technology in the paper pulping process." Li, M.; Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. Sep. Sci. Technol. 36, 835-847 (2001).

31. "Electrochemical properties of natural carotenoids." Liu, D.; Gao, Y.; Kispert, L. D. Curr. Sep. 19, 93 (2001).

32. "Electrochemical and Spectroelectrochemical Study of 7,7'-Diapo-(7E,7'Z)-diphenylcarotene." Liu, D.; Kispert, L. D. J. Phys. Chem. B 105, 975-980 (2001).

33. "Syntheses and Characterizations of Metal Complexes Derived from cis,cis-1,3,5-Triaminocyclohexane-N,N',N''-triacetic Acid." Luo, H.; Eberly, N.; Rogers, R. D.; Brechbiel, M. W. Inorg. Chem. 40, 493-498 (2001).

34. "A convenient and selective route to a trans-difunctionalized macrocyclic hexadentate N₄O₂ ligand." Luo, H.; Rogers, R. D.; Brechbiel, M. W. Can. J. Chem. 79, 1105-1109 (2001).

35. "Oxidation methods for aromatic diazines: substituted pyrazine-N-oxides, pyrazine-N,N'-dioxides, and 2,2':6',2"-terpyridine-1,1"-dioxide." McKay, S. E.; Sooter, J. A.; Bodige, S. G.; Blackstock, S. C. Heterocyclic Commun. 7, 307-312 (2001).

36. "Electrical rectification by a monolayer of hexadecylquinolinium tricyanoquinodimethanide sandwiched between gold electrodes." Metzger, R. M. Mater. Res. Soc. Symp. Proc. 660, JJ9.8/1-JJ9.8/6 (2001).

37. "The quest for unimolecular rectification from Oxford to Waltham to Exeter to Tuscaloosa." Metzger, R. M. J. Macromol. Sci., Pure Appl. Chem. A38, 1499-1517 (2001).

38. "Rectification by a single molecule." Metzger, R. M. Synthetic Metals 124, 107-112 (2001).

39. "Unimolecular electrical rectification down to 105 K, and spectroscopy of hexadecylquinolinium tricyanoquinodimethanide." Metzger, R. M. Mater. Res. Soc. Symp. Proc. 582, H12.2/1-H12.2/6 (2001).

40. "Unimolecular organic rectifier of electrical current," Metzger, R. M.; Chen, B., US Patent 6,169,291, 2001.

41. "Unimolecular rectification between 370 K and 105 K and spectroscopic properties of hexadecylquinolinium tricyanoquinodimethanide." Metzger, R. M.; Chen, B.; Baldwin, J. W. ACS Symposium Series 798, 50-65 (2001).

42. "Magnetic nanoparticle arrays with ultra-uniform length electrodeposited in highly ordered alumina nanopores ("alumite")." Metzger, R. M.; Sun, M.; Zangari, G.; Shamsuzzoha, M. Mater. Res. Soc. Symp. Proc. 636, D9.33/1-D9.33/6 (2001).

43. "Electrical Rectification by a Monolayer of Hexadecylquinolinium Tricyanoquinodimethanide Measured between Macroscopic Gold Electrodes." Metzger, R. M.; Xu, T.; Peterson, I. R. J. Phys. Chem. B 105, 7280-7290 (2001).

44. "Solution conformation of the Met 61 to His 61 mutant of Pseudomonas stutzeri ZoBell ferrocytochrome c-551." Miller, G. T.; Hardman, J. K.; Timkovich, R. Biophys. J. 80, 2928-2934 (2001).

45. "Spectroscopic analysis of the tribological behavior of a model boundary layer lubricant." Nichols, A., Jr.; Street, S. C. Analyst 126, 1269-1273 (2001).

46. "Materials science in general chemistry for freshman engineering majors." Nikles, D. E. J. Mater. Ed. 22, 71-76 (2001).

47. "Pollution prevention in the magnetic tape industry: solventless coating formulations for magnetic tape manufacture." Nikles, D. E.; Ellison, M. M.; Huh, J. Y.; Parakka, J. P.; Power, A. ACS Symposium Series 766, 18-28 (2001).

48. "Ethyl lactate: a green solvent for magnetic tape coating." Nikles, S. M.; Piao, M.; Lane, A. M.; Nikles, D. E. Green Chem. 3, 109-113 (2001).

49. "Synthesis of novel 1,3,5-cis,cis-triaminocyclohexane ligand based Cu(II) complexes as potential radiopharmaceuticals and correlation of structure and serum stability." Park, G.; Dadachova, E.; Przyborowska, A.; Lai, S.-j.; Ma, D.; Broker, G.; Rogers, R. D.; Planalp, R. P.; Brechbiel, M. W. Polyhedron 20, 3155-3163 (2001).

50. "Copper(II) Complexes of Novel N-Alkylated Derivatives of cis,cis-1,3,5-Triaminocyclohexane. 1. Preparation and Structure." Park, G.; Shao, J.; Lu, F. H.; Rogers, R. D.; Chasteen, N. D.; Brechbiel, M. W.; Planalp, R. P. Inorg. Chem. 40, 4167-4175 (2001).

51. "Analytical Model for Molecular-Scale Charge Transport." Peterson, I. R.; Vuillaume, D.; Metzger, R. M. J. Phys. Chem. A 105, 4702-4707 (2001).

52. "One-electron transfer product of quinone addition to carotenoids EPR and optical absorption studies." Polyakov, N. E.; Konovalov, V. V.; Leshina, T. V.; Luzina, O. A.; Salakhutdinov, N. F.; Konovalova, T. A.; Kispert, L. D. J. Photochem. Photobiol., A: Chem. 141, 117-126 (2001).

53. "Carotenoids as antioxidants: spin trapping EPR and optical study." Polyakov, N. E.; Kruppa, A. I.; Leshina, T. V.; Konovalova, T. A.; Kispert, L. D. Free Rad. Biol. Med. 31, 43-52 (2001).

54. "Carotenoids as scavengers of free radicals in a Fenton reaction: antioxidants or pro-oxidants?" Polyakov, N. E.; Leshina, T. V.; Konovalova, T. A.; Kispert, L. D. Free Rad. Biol. Med. 31, 398-404 (2001).

55. "A convenient protecting group for aldehydes." Quan, L. G.; Cha, J. K. Synlett, 1925-1926 (2001).

56. "Reductive cyclization of enones by titanium(IV) aryloxide and a Grignard reagent." Quan, L. G.; Cha, J. K. Tetrahedron Lett. 42, 8567-8569 (2001).

57. "Titanium-Mediated Alkylative Cyclizations of 1,3-Diene-Tethered Esters." Quan, L. G.; Cha, J. K. Org. Lett. 3, 2745-2748 (2001).

58. "Dendrimer-mediated growth of very flat ultrathin Au films." Rar, A.; Zhou, J. N.; Liu, W. J.; Barnard, J. A.; Bennett, A.; Street, S. C. Appl. Surf. Sci. 175-176, 134-139 (2001).

59. "Sterically demanding, water-soluble alkylphosphines as ligands for high activity Suzuki coupling of aryl bromides in aqueous solvents." Shaughnessy, K. H.; Booth, R. S. Org. Lett. 3, 2757-2759 (2001).

60. "The stability of the biomimetic cation triaqua-μ-oxohexapropionatotrichromium(III) in vivo in rats." Shute, A. A.; Chakov, N. E.; Vincent, J. B. Polyhedron 20, 2241-2252 (2001).

61. "Preparation of the first ortho-substituted pentafluorosulfanylbenzenes." Sipyagin, A. M.; Bateman, C. P.; Tan, Y.-T.; Thrasher, J. S. J. Fluorine Chem. 112, 287-295 (2001).

62. "A Stable Dirhodium Tetracarboxylate Carbenoid: Crystal Structure, Bonding Analysis, and Catalysis." Snyder, J. P.; Padwa, A.; Stengel, T.; Arduengo, A. J., III; Jockisch, A.; Kim, H.-J. J. Am. Chem. Soc. 123, 11318-11319 (2001).

63. "Green separation science and technology: replacement of volatile organic compounds in industrial scale liquid-liquid or chromatographic separations." Spear, S. K.; Visser, A. E.; Willauer, H. D.; Swatloski, R. P.; Griffin, S. T.; Huddleston, J. G.; Rogers, R. D. ACS Symposium Series 766, 206-221 (2001).

64. "Unique Structural and Mechanical Properties of Ultrathin Au Films Grown on Dendrimer-Mediated Substrates." Street, S. C.; Rar, A.; Zhou, J. N.; Liu, W. J.; Barnard, J. A. Chem. Mater. 13, 3669-3677 (2001).

65. "Electrodeposition of highly uniform magnetic nanoparticle arrays in ordered alumite." Sun, M.; Zangari, G.; Shamsuzzoha, M.; Metzger, R. M. Appl. Phys. Lett. 78, 2964-2966 (2001).

66. "Solvation of 1-butyl-3-methylimidazolium hexafluorophosphate in aqueous ethanol-a green solution for dissolving 'hydrophobic' ionic liquids." Swatloski, R. P.; Visser, A. E.; Reichert, W. M.; Broker, G. A.; Farina, L. M.; Holbrey, J. D.; Rogers, R. D. Chem. Commun., 2070-2071 (2001).

67. "The bioinorganic chemistry of chromium(III)." Vincent, J. B. Polyhedron 20, 1-26 (2001).

68. "Use of triaqua-μ³-oxohexakis-mu-propionatotrichromium (1+), [Cr₃O(O₂CCH₂CH₃)₆(H₂O)₃]⁺, as a nutritional supplement or in treatment of medical conditions," Vincent, J. B.; Davis, C. M., US Patent 6,197,816, 2001.

69. "Hydrophobic ionic liquids incorporating N-alkylisoquinolinium cations and their utilization in liquid-liquid separations." Visser, A. E.; Holbrey, J. D.; Rogers, R. D. Chem. Commun., 2484-2485 (2001).

70. "Liquid/liquid extraction of metal ions in room temperature ionic liquids." Visser, A. E.; Swatloski, R. P.; Griffin, S. T.; Hartman, D. H.; Rogers, R. D. Sep. Sci. Technol. 36, 785-804 (2001).

71. "Task-specific ionic liquids for the extraction of metal ions from aqueous solutions." Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Davis, J. H., Jr.; Rogers, R. D.; Mayton, R.; Sheff, S.; Wierzbicki, A. Chem. Commun., 135-136 (2001).

72. "Surface chemistry and dispersion of magnetic pigment for a solventless process." Woo, T.; Huh, J. Y.; Nikles, D. E. IEEE Trans. Magn. 37, 1634-1636 (2001).

73. "Aluminum reduction via near room temperature electrolysis in ionic liquids." Wu, B.; Reddy, R. G.; Rogers, R. D. Light Metals, 237-243 (2001).

74. "Light-induced enhancement of rectification by monolayer of hexadecylquinolinium tricyanoquinodimethanide between Al electrodes." Xu, T.; Metzger, R. M. Mater. Res. Soc. Symp. Proc. 660, JJ10.8/1-JJ10.8/5 (2001).

75. "Rectification by a monolayer of hexadecylquinolinium tricyanoquinodimethanide between gold electrodes." Xu, T.; Peterson, I. R.; Lakshmikantham, M. V.; Metzger, R. M. Angew. Chem., Int. Ed. 40, 1749-1752 (2001).

76. "Electrophilic Cyclizations of Vinylcyclopropanols to Tethered Aldehydes." Youn, J.-H.; Lee, J.; Cha, J. K. Org. Lett. 3, 2935-2938 (2001).

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