Department Faculty Publications

Chemistry Department faculty publications from 2002:

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1. "Condensed Thiophenes and Selenophenes: Thionyl Chloride and Selenium Oxychloride as Sulfur and Selenium Transfer Reagents." Amaresh, R. R.; Lakshmikantham, M. V.; Baldwin, J. W.; Cava, M. P.; Metzger, R. M.; Rogers, R. D. J. Org. Chem. 67, 2453-2458 (2002).

2. "Patterned thin films of polyamidoamine dendrimers formed using microcontact printing." Arrington, D.; Curry, M.; Street, S. C. Langmuir 18, 7788-7791 (2002).

3. "Whatever happened to shear-flocculation." Bakker, M. G.; Spears, D. R.; Murphy, D. D.; Turner, G. L. Fluid/Part. Sep. J. 14, 155-168 (2002).

4. "Rectification and nonlinear optical properties of a Langmuir-Blodgett monolayer of a pyridinium dye." Baldwin, J. W.; Amaresh, R. R.; Peterson, I. R.; Shumate, W. J.; Cava, M. P.; Amiri, M. A.; Hamilton, R.; Ashwell, G. J.; Metzger, R. M. J. Phys. Chem. B 106, 12158-12164 (2002).

5. "Green chemistry and lanthanide-based crystal engineering." Broker, G. A.; Klingshirn, M. A.; Rogers, R. D. J. Alloys Comp. 344, 123-127 (2002).

6. "Synthesis of spherical FePd and CoPt nanoparticles." Chen, M.; Nikles, D. E. J. Appl. Phys. 91, 8477-8479 (2002).

7. "Synthesis, self-assembly, and magnetic properties of Fe_xCo_yPt_100-x-y nanoparticles." Chen, M.; Nikles, D. E. Nano Letters 2, 211-214 (2002).

8. "Stereoselective and regioselective synthesis of azepane and azepine derivatives via piperidine ring expansion." Chong, H.-s.; Ganguly, B.; Broker, G. A.; Rogers, R. D.; Brechbiel, M. W. J. Chem. Soc., Perkin Trans. 1, 2080-2086 (2002).

9. "In vivo interactions between photosynthesis, mitorespiration, and chlororespiration in Chlamydomonas reinhardtii." Cournac, L.; Latouche, G.; Cerovic, Z.; Redding, K.; Ravenel, J.; Peltier, G. Plant Phys. 129, 1921-1928 (2002).

10. "On the UV curability and mechanical properties of novel binder systems derived from poly(ethylene terephthalate) (PET) waste for solventless magnetic tape manufacturing, 2 methacrylated oligoesters." Farahat, M. S.; Nikles, D. E. Macromol. Mater. Eng. 287, 353-362 (2002).

11. "Fluoroaromatic universal bases in peptide nucleic acids." Frey, K. A.; Woski, S. A. Chem. Commun., 2206-2207 (2002).

12. "Electron Transfer of Carotenoids Imbedded in MCM-41 and Ti-MCM-41: EPR, ENDOR, and UV-Vis Studies." Gao, Y.; Konovalova, T. A.; Xu, T.; Kispert, L. D. J. Phys. Chem. B 106, 10808-10815 (2002).

13. "Evaluation of Polymer-Based Aqueous Biphasic Systems As Improvement for the Hardwood Alkaline Pulping Process." Guo, Z.; Li, M.; Willauer, H. D.; Huddleston, J. G.; April, G. C.; Rogers, R. D. Ind. Eng. Chem. Res. 41, 2535-2542 (2002).

14. "Iodine-Catalyzed R/S Isomerization of Allenic Carotenoids." He, Z.; Gao, G.; Hand, E. S.; Kispert, L. D.; Strand, A.; Liaaen-Jensen, S. J. Phys. Chem. A 106, 2520-2525 (2002).

15. "In vivo distribution of chromium from chromium picolinate in rats and implications for the safety of the dietary supplement." Hepburn, D. D. D.; Vincent, J. B. Chem. Res. Toxicol. 15, 93-100 (2002).

16. "Efficient, halide free synthesis of new, low cost ionic liquids: 1,3-dialkylimidazolium salts containing methyl- and ethyl-sulfate anions." Holbrey, J. D.; Reichert, W. M.; Swatloski, R. P.; Broker, G. A.; Pitner, W. R.; Seddon, K. R.; Rogers, R. D. Green Chem. 4, 407-413 (2002).

17. "Green chemistry and ionic liquids: Synergies and ironies." Holbrey, J. D.; Rogers, R. D. ACS Symposium Series 818, 2-14 (2002).

18. "Green industrial applications of ionic liquids: Technology review." Holbrey, J. D.; Rogers, R. D. ACS Symposium Series 818, 446-458 (2002).

19. "Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages." Hong, K.; Zhang, H.; Mays, J. W.; Visser, A. E.; Brazel, C. S.; Holbrey, J. D.; Reichert, W. M.; Rogers, R. D. Chem. Commun., 1368-1369 (2002).

20. "Free-energy relationships and solvatochromatic properties of 1-alkyl-3-methylimidazolium ionic liquids." Huddleston, J. G.; Broker, G. A.; Willauer, H. D.; Rogers, R. D. ACS Symposium Series 818, 270-288 (2002).

21. "The solvatochromic properties, α, β, and π*, of PEG-salt aqueous biphasic systems." Huddleston, J. G.; Willauer, H. D.; Rogers, R. D. Phys. Chem. Chem. Phys. 4, 4065-4070 (2002).

22. "Reduction of the fcc. to L10 ordering temperature for self-assembled FePt nanoparticles containing Ag." Kang, S.; Harrell, J. W.; Nikles, D. E. Nano Letters 2, 1033-1036 (2002).

23. "Correlation of the Melting Points of Potential Ionic Liquids (Imidazolium Bromides and Benzimidazolium Bromides) Using the CODESSA Program." Katritzky, A. R.; Jain, R.; Lomaka, A.; Petrukhin, R.; Karelson, M.; Visser, A. E.; Rogers, R. D. J. Chem. Inf. & Comp. Sci. 42, 225-231 (2002).

24. "QSPR Correlation of the Melting Point for Pyridinium Bromides, Potential Ionic Liquids." Katritzky, A. R.; Lomaka, A.; Petrukhin, R.; Jain, R.; Karelson, M.; Visser, A. E.; Rogers, R. D. J. Chem. Inf. & Comp. Sci. 42, 71-74 (2002).

25. "Patterned Redox Arrays of Polyarylamines II. Growth of Thin Films and Their Electrochemical Behavior." Kim, K.-Y.; Hassenzahl, J. D.; Selby, T. D.; Szulczewski, G. J.; Blackstock, S. C. Chem. Mater. 14, 1691-1694 (2002).

26. "Regio- and stereochemistry of inter- and intramolecular titanium-mediated coupling of imides and mono-substituted olefins." Kim, S.-H.; Park, Y.; Choo, H.; Cha, J. K. Tetrahedron Lett. 43, 6657-6660 (2002).

27. "Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts." Klingshirn, M. A.; Broker, G. A.; Holbrey, J. D.; Shaughnessy, K. H.; Rogers, R. D. Chem. Commun., 1394-1395 (2002).

28. "A Thiol-Substituted Carotenoid Self-Assembles on Gold Surfaces." Liu, D.; Szulczewski, G. J.; Kispert, L. D.; Primak, A.; Moore, T. A.; Moore, A. L.; Gust, D. J. Phys. Chem. B 106, 2933-2936 (2002).

29. "The direct synthesis of trifluoronitromethane, CF₃NO₂." Lu, N.; Thrasher, J. S. J. Fluorine Chem. 117, 181-184 (2002).

30. "Polymer formation in room temperature ionic liquids," Mays, J. W.; Bu, L.; Rogers, R. D.; Hong, K.; Zhang, H., PCT Int. Appl. WO 2002079269, 2002.

31. "Monolayer rectifiers." Metzger, R. M. J. Sol. State Chem. 168, 696-711 (2002).

32. "The Effects of Mercury Adsorption on the Optical Response of Size-Selected Gold and Silver Nanoparticles." Morris, T.; Copeland, H.; McLinden, E.; Wilson, S.; Szulczewski, G. Langmuir 18, 7261-7264 (2002).

33. "Synthesis and Characterization of Gold Sulfide Nanoparticles." Morris, T.; Copeland, H.; Szulczewski, G. Langmuir 18, 535-539 (2002).

34. "A Spectroscopic Study of Mercury Vapor Adsorption on Gold Nanoparticle Films." Morris, T.; Kloepper, K.; Wilson, S.; Szulczewski, G. J. Coll. Interface Sci. 254, 49-55 (2002).

35. "Evaluating the Role of Coinage Metal Films in the Detection of Mercury Vapor by Surface Plasmon Resonance Spectroscopy." Morris, T.; Szulczewski, G. Langmuir 18, 5823-5829 (2002).

36. "A Spectroscopic Ellipsometry, Surface Plasmon Resonance, and x-ray Photoelectron Spectroscopy Study of Hg Adsorption on Gold Surfaces." Morris, T.; Szulczewski, G. Langmuir 18, 2260-2264 (2002).

37. "Radical Fragmentation of w-Bromoalkyl Cyclobutanones. A Modular Approach to Eight-Membered Carbocycles." Oh, H.-S.; Lee, H. I.; Cha, J. K. Org. Lett. 4, 3707-3709 (2002).

38. "[4 + 3]-Cycloaddition of aminoallyl cations with 1,3-dienes: 11-oxatricyclo[4.3.1.12,5]undec-3-en-10-one." Oh, J.; Ziani-Cherif, C.; Choi, J.-R.; Cha, J. K. Org. Synth. 78, 212-219 (2002).

39. "Effects of peptide chain length on the gas-phase proton transfer properties of doubly-protonated ions from bradykinin and its N-terminal fragment peptides." Pallante, G. A.; Cassady, C. J. Int. J. Mass Spectrom. 219, 115-131 (2002).

40. "The role of radicals in the phototransformations of b-ionone in the presence of electron donors in solution." Polyakov, N. E.; Kruppa, A. I.; Bashurova, V. S.; Leshina, T. V.; Kispert, L. D. J. Photochem. Photobiol., A: Chem. 153, 113-119 (2002).

41. "Preparation of Isoprostanes and Neuroprostanes." Quan, L. G.; Cha, J. K. J. Am. Chem. Soc. 124, 12424-12425 (2002).

42. "Diastereoselective synthesis of trans-1,2-dialkylcyclopropanols by the Kulinkovich hydroxycyclopropanation of homoallylic alcohols." Quan, L. G.; Kim, S.-H.; Lee, J. C.; Cha, J. K. Angew. Chem., Int. Ed. 41, 2160-2162 (2002).

43. "4-Phenyl-2-methylene-1,3-diselenole: synthesis and reactions." Rajagopal, D.; Lakshmikantham, M. V.; Cava, M. P. Sulfur Letters 25, 129-133 (2002).

44. "Synthesis of the First 1,3-Ditellurole-Containing Radialene-Type TTF Derivatives." Rajagopal, D.; Lakshmikantham, M. V.; Cava, M. P. Org. Lett. 4, 2581-2583 (2002).

45. "Generation of the First Tellurium-Containing Diheteropentalene." Rajagopal, D.; Lakshmikantham, M. V.; Morkved, E. H.; Cava, M. P. Org. Lett. 4, 1193-1195 (2002).

46. "Thin metal films deposited on dendrimer monolayers." Rar, A.; Curry, M.; Barnard, J. A.; Street, S. C. Tribology Letters 12, 87-94 (2002).

47. "Spectroscopic studies of the dodecanuclear chromium complex Cr₁₂O₉(OH)₃(pivalate)₁₅: confirmation of the presence of twelve Cr(III) centers and the crystal structure of Cr₁₂O₉(OH)₃(pivalate)₁₅·2PrOH·9H₂O." Royer, A. C.; Rogers, R. D.; Arrington, D. L.; Street, S. C.; Vincent, J. B. Polyhedron 21, 155-165 (2002).

48. "Application of ionic liquids as plasticizers for poly(methyl methacrylate)." Scott, M. P.; Brazel, C. S.; Benton, M. G.; Mays, J. W.; Holbrey, J. D.; Rogers, R. D. Chem. Commun., 1370-1371 (2002).

49. "Supported ionic liquid membranes and facilitated ionic liquid membranes." Scovazzo, P.; Visser, A. E.; Davis, J. H., Jr.; Rogers, R. D.; Koval, C. A.; DuBois, D. L.; Noble, R. D. ACS Symposium Series 818, 69-87 (2002).

50. "Patterned redox arrays of polyarylamines I. Synthesis and electrochemistry of a p-phenylenediamine and arylamino-appended p-phenylenediamine arrays." Selby, T. D.; Kim, K.-Y.; Blackstock, S. C. Chem. Mater. 14, 1685-1690 (2002).

51. "Acid-mediated, chromium-catalyzed allylation of aldehydes." Shaughnessy, K. H.; Huang, R. Synth. Comm. 32, 1923-1928 (2002).

52. "The fate of the biomimetic cation triaqua-μ-oxohexapropionatotrichromium(III) in rats." Shute, A. A.; Vincent, J. B. J. Inorg. Biochem. 89, 272-278 (2002).

53. "1-Chloro-2,6-dinitro-4-[(perfluoroalkyl)thio]benzenes in the synthesis of heterocycles." Sipyagin, S. M.; Enshov, V. S.; Kashtanov, S. A.; Thrasher, J. S. Chem. Het. Compounds 38, 1375-1381 (2002).

54. "The biomimetic [Cr₃O(O₂CCH₂CH₃)₆(H₂O)₃]⁺ decreases plasma insulin, cholesterol, and triglycerides in healthy and type II diabetic rats but not type I diabetic rats." Sun, Y.; Clodfelder, B. J.; Shute, A. A.; Irvin, T.; Vincent, J. B. J. Biol. Inorg. Chem. 7, 852-862 (2002).

55. "Dissolution of cellulose with ionic liquids." Swatloski, R. P.; Spear, S. K.; Holbrey, J. D.; Rogers, R. D. J. Am. Chem. Soc. 124, 4974-4975 (2002).

56. "On the solubilization of water with ethanol in hydrophobic hexafluorophosphate ionic liquids." Swatloski, R. P.; Visser, A. E.; Reichert, W. M.; Broker, G. A.; Farina, L. M.; Holbrey, J. D.; Rogers, R. D. Green Chem. 4, 81-87 (2002).

57. "Characterization of hydrophilic and hydrophobic ionic liquids: Alternatives to volatile organic compounds for liquid-liquid separations." Visser, A. E.; Reichert, W. M.; Swatloski, R. P.; Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. ACS Symposium Series 818, 289-308 (2002).

58. "Task-Specific Ionic Liquids Incorporating Novel Cations for the Coordination and Extraction of Hg²⁺ and Cd²⁺: Synthesis, Characterization, and Extraction Studies." Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Mayton, R.; Sheff, S.; Wierzbicki, A.; Davis, J. H., Jr.; Rogers, R. D. Env. Sci. Technol. 36, 2523-2529 (2002).

59. "Solute Partitioning in Aqueous Biphasic Systems Composed of Polyethylene Glycol and Salt: The Partitioning of Small Neutral Organic Species." Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. Ind. Eng. Chem. Res. 41, 1892-1904 (2002).

60. "Solvent Properties of Aqueous Biphasic Systems Composed of Polyethylene Glycol and Salt Characterized by the Free Energy of Transfer of a Methylene Group between the Phases and by a Linear Solvation Energy Relationship." Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. Ind. Eng. Chem. Res. 41, 2591-2601 (2002).

61. "Nanoscratch behavior of sputtered metal films on PAMAM dendrimer monolayers." Xu, F.-T.; Curry, M.; Huang, F.; Ye, P.-P.; Rar, A.; Street, S. C.; Barnard, J. A. Mater. Res. Soc. Symp. Proc. 710, 253-258 (2002).

62. "Molecular interlayers and the mechanism of abrasive wear of ultrathin metal films." Xu, F. T.; Ye, P. P.; Curry, M.; Barnard, J. A.; Street, S. C. Tribology Letters 12, 189-193 (2002).

63. "Nanoditches Fabricated Using a Carbon Nanotube as a Contact Mask." Xu, T.; Metzger, R. M. Nano Letters 2, 1061-1065 (2002).

64. "A Spectroscopic Study of Hexadecylquinolinium Tricyanoquinodimethanide as a Monolayer and in Bulk." Xu, T.; Morris, T. A.; Szulczewski, G. J.; Amaresh, R. R.; Gao, Y.; Street, S. C.; Kispert, L. D.; Metzger, R. M.; Terenziani, F. J. Phys. Chem. B 106, 10374-10381 (2002).

65. "Current-voltage characteristics of an LB monolayer of didecylammonium tricyanoquinodimethanide measured between macroscopic gold electrodes." Xu, T.; Morris, T. A.; Szulczewski, G. J.; Metzger, R. M.; Szablewski, M. J. Mater. Chem. 12, 3167-3171 (2002).

66. "Periodic holes with 10 nm diameter produced by grazing Ar+ milling of the barrier layer in hexagonally ordered nanoporous alumina." Xu, T.; Zangari, G.; Metzger, R. M. Nano Letters 2, 37-41 (2002).

67. "Synthesis of chiral trans-anti-trans-isomers of dicyclohexano-18-crown-6 via an enzymatic reaction and the solid-state structure of one enantiomer." Yamato, K.; Bartsch, R. A.; Broker, G. A.; Rogers, R. D.; Dietz, M. L. Tetrahedron Lett. 43, 5805-5808 (2002).

68. "Improved stereospecific synthesis of the trans isomers of dicyclohexano-18-crown-6 and the solid-state structure of the trans-syn-trans-isomer." Yamato, K.; Bartsch, R. A.; Dietz, M. L.; Rogers, R. D. Tetrahedron Lett. 43, 2153-2156 (2002).

69. "Identification of hemes and related cyclic tetrapyrroles by matrix-assisted laser desorption/ionization and liquid secondary ion mass spectrometry." Youn, H.-S.; Burkhalter, R. S.; Timkovich, R. Rapid. Commun. Mass Spectrom. 16, 1147-1152 (2002).

70. "Homopolymerization and block copolymer formation in room-temperature ionic liquids using conventional free-radical initiators." Zhang, H.; Bu, L.; Li, M.; Hong, K.; Visser, A. E.; Rogers, R. D.; Mays, J. W. ACS Symposium Series 818, 114-124 (2002).

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